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Brookfield AMETEK

Chocolate

Laboratory Viscometer Application Data Sheet

Use

Chocolate is used in making a wide variety of desserts and treats, including candies, icings, pastry fillings and desserts, to name a few.

Test Equipment

  • Viscometer/Rheometer Spring Torque Range: HA
  • Spindle: SC4-27 with SC4-13RPY Sample Chamber
  • Accessories: Small Sample Adapter, TC-502P Programmable Temperature Bath
  • Speed, rpm: 5, 10, 20, 50 and 100
  • Temperature: 40°C

* While a particular model/version may be used as an example in this method, any current or past model/version from the same series may also be used. Please consult a sales associate to discuss the most current instrumentation and software available.

Test Method

The National Confectioners Association and Chocolate Manufacturers Association specify a chocolate test procedure using Brookfield equipment such as those listed above. The Small Sample Adapter may be used with various Brookfield Viscometers or Rheometers. We used a Brookfield HADV-III Ultra Rheometer with SC4-27 hanging link spindle for our example, however, many customers use the HADV-II+ Pro Viscometer instead. The SC4-13RPY sample chamber has an integral temperature probe that connects with its cable to the rheometer, to provide temperature readout. The test temperature of 40°C was maintained by connecting the Small Sample Adapter water jacket to a Brookfield TC-502P Programmable Refrigerated Bath.

Rheocalc v3.2 software provides automated instrument control and data acquisition. It controls both the rheometer speeds and the bath temperature. Representative data from the analyses are shown in Figures 1 and 2 below:


Figure 1: Chocolate Behavior at 40°C.

Figure 1 demonstrates that the viscosity of the dark chocolate decreased as the speed increased. This behavior is known as "shear- thinning".


Figure 2: NCA/CMA Casson Plot of Chocolate Rheology at 40°C.

Figure 2, generated in the Rheocalc™ Analysis module, compares the calculated NCA/CMA Casson model values to the measured data. The Confidence of Fit (%) or "CoF" is nearly 100%, signifying an excellent fit of the model to the data. The Plastic Viscosity is 1241 cP and the Yield Stress is 129.2 Pa. These parameters provide important measures of how the molten chocolate will flow and enrobe, for example.

The viscosity value, cP, at 20 rpm, measured with HA-range viscometer and SC4-27 spindle, correlates with Degrees MacMichael or "deg. M": deg. M = (Torque, %)x(3.40) or [(Viscosity, cP)/(250)]x(3.40). Therefore, in our example, 31.4% Torque and 7850 cP at 20 rpm correspond to 107 deg. M.

Finally, it should be noted that chocolates are actually thixotropic - that is, shear-thinning over time at a constant shear rate. The advantage of the NCA/CMA method is that it provides a standardized test procedure - and thus better reproducibility. The test procedure is discussed in Article Reprints, particularly AR-99 and AR-79, available from Brookfield AMETEK - please contact us if you want us to mail copies of these article reprints.